COMPRES Newsletter

May, 2003 Volume 2 No. 2

Table of Contents

Information Update

  1. Progress of COMPRES projects and the first annual report

  2. The proposed second-year (2003-2004)COMPRES Budget

  3. Notes of the first-year (2002-2003)COMPRES central office Budget

  4. COMPRES workshop on High Pressure Earth and Planetary Sciences: Our Planet from Surface to Center and Beyond was held on March 22-23 at Miami, Florida

  5. The conference on Mantle Composition, Structure, and Phase Transitions was held on April 2-6 in Frejus, France

  6. COMPRES executive committee members meet biweekly through internet video conference system

  7. New High-Pressure Beamlines at the NSLS nearing completion

  8. COMPRES searchable database

  9. Membership status

  10. Education and Outreach: Networking with National Organizations

  11. President search

  12. High-pressure facilities at the ALS: Call for proposals

Reports

Multi-anvil cell assembly project

NICEST JINS Workshop

Coming events

Second COMPRES annual meeting, Santa Cruz, June 18-20

Workshops at the 2003 NSLS Annual Users' Meeting, High Pressure Mineral Physics Using Synchrotron Radiation, Upton, New York, May 21

Opportunities

Communication and Newsletter input

COMPRES Contacts



Information Update

1. Progress of COMPRES projects and the first annual report

The COMPRES management mechanism requires that each COMPRES related project be administered and reviewed by each corresponding committee. A recent review by Infrastructure Development Committee and Community Facilities Committee indicates that all the administered projects are making satisfactory progress. The first annual report regarding the project progress and the second year projection has been submitted to the NSF. The annual report is currently available at the COMPRES web site: http://www.compres.stonybrook.edu/Publications.  

2. The proposed second-year (2003-2004) COMPRES Budget (in k$)

COMPRES Central Office (Stony Brook):   $424k

Including:

Salaries for the President and Administration Assistant  
  New Student Intern Program*  
  Meetings/Workshop  
  Supplies  

IDC:

IDC: $132k
Infrastructure Development

 

 
  Development of Laser Heated Diamond Cell (Princeton): $180k
  Neutron Studies at National Facilities (Virginia Tech.): $  70k
  Multi-anvil Cell Assembly Development and Production (ASU): $156k
  Pressure and Temperature Calibration  
 

Geophysical Lab:

$125k
 

University of Colorado:

$  80k
  Brillouin Lab at Advanced Photon Source:  A Community Resource  
 

University of Illinois at Urbana-Champaign:

$229k
Community Facilities    
  Multi-anvil High Pressure at National Synchrotron Light Source (SB): $331k
  West-Coast Synchrotron Facilities (UC Berkeley): $175k
  Megabar Synchrotron Center at the NSLS (GL): $298k
Total:                                                                                                                  $2,200k

* Student Intern Program.

This year we are seeking support for two student internships.  This experimental educational program had to be cut from the first year budget, but was well received by NSF and has been restored to the year 2 budget. The funding of this project is added to the budget with no harm to ongoing programs.  Graduate students in 2nd or 3rd years with interests in high pressure Earth sciences will be recruited from Earth science departments. They will work, at employee salaries, at one of the national facilities. They will support outside users as well as master techniques using the system. They then return to their graduate program and resume their PhD study. The new internship program is designed with the following goals:

·        Provide needed beamline support for users at the national facilities.

·        Provide in-depth training to individuals with PhD level career goals in high-pressure research in the use of national facilities.

·        Provide expertise at many Universities of national facilities upon return of the intern to the graduate program.

3. Notes of the first-year (2002-2003) COMPRES Central Office Budget

The first-year COMPRES Central Office budget included personnel expenses for the President (Jay Bass) and the Administration Assistant (Ann Lattimore). In addition, $84k (68% rest of the direct cost) was used to support the participants of COMPRES workshops and meetings, $15k was used for cost sharing of internet video conference system purchase, $14k was used for COMPRES central operation (advertisements, visitor accommodation, computer and printing services, etc.), and $9k went to COMPRES education program.

4. COMPRES workshop on High Pressure Earth and Planetary Sciences

Upon the request by NSF, a COMPRES workshop on High Pressure Earth and Planetary Sciences: Our Planet from Surface to Center and Beyond was held on March 22-23 at Miami, Florida. Over 50 scientists from universities, national labs and overseas institutions attended the workshop. Dr. David Lambert from Earth Sciences Division of NSF also attended the workshop and gave a brief introduction to the division and NSF’s expectation from the workshop. Discussions were focused on four major topics: Near Surface Processes, Subduction and the Mantle, the Core and CMB, and Planetary Geology and Impacts. The participants reviewed the scientific advances in these areas in the past decade, significant technologies that enabled the advances, and the current most important issues for future research. Expertise gathered at the workshop extended beyond mineral physics and included seismology and synchrotron x-ray instrumentation. A brief report of the workshop to NSF was sent in on May 1, and a published brochure on the Future of High Pressure Earth and Planetary Sciences is expected in August.

5. The conference on Mantle Composition, Structure, and Phase Transitions was held on April 2-6 in Frejus, France

Over 60 scientists from a number of countries discussed topics in geochemistry, mineral physics, geodynamics, and seismology.  Presentations included broad state-of-the-field review, and latest research results on a diverse range of subjects including the core-mantle boundary, core-mantle interactions, composition of the lower mantle and transition zone, geochemical reservoirs, seismic structure of the mantle,  plumes,  mantle  convection, high P-T phase transitions, electronic transition in minerals, etc. Invited speakers included Stan Hart, John Brodholdt, Denis Andrault, David Bercovici, Mike Brown, Geoff Davies, Rob van der Hilst, Don Helmberger, Yannick Ricard, Guillaume Fiquet, Don Weidner, Michael Weber, Michael Manga, Kei Hirose, Philippe Gillet, Alex Rocholl, and Renata Wentzcovitch. The meeting was co-sponsored by COMPRES (USA), CNRS (France), the GeoForschungsZentrum (Potsdam, Germany), and the Japan Ministry of Science & Education. Organizers were Jan Matas, T Katsura, F Schilling, and J Bass.

6. COMPRES executive committee members meet biweekly through internet video conference system

Internet technology has brought COMPRES executive committee members together twice a month for steering the COMPRES operation since beginning of this year. To avoid exhausting travels, interruption of teaching and high costs of operation, COMPRES executive committee has started to hold the business meeting through internet video conference system. Every other Monday, the committee members meet together from their home institutions to discuss the operation of COMPRES. “It has been very successful.” said Weidner, Chair of the Committee, “Not only has it saved the travel and the cost, but also, most importantly, this makes it possible for the committee members to meet as often as twice or three times a month which is absolutely needed to ensure success of COMPRES.” He also suggests the other subcommittee should also set a similar routine for meeting. Currently COMPRES is renting a central video conference bridge system from University of Illinois at Urbana-Champaign on an hourly basis for the biweekly meeting. COMPRES are buying such a system so that other committees may also hold their business meetings on a regular base through the internet video conference system. 

7. New High-Pressure Beamlines at the NSLS nearing completion

The conversion of the medical beamline to two new high-pressure facilities at the National Synchrotron Light Source is now complete.  Both X17B2 (Large Volume Multianvil) and X17B3 (Diamond Anvil Cell) have passed their radiation surveys. When installation of the high-pressure equipment is complete, they both should be ready for business.  We have been accepting proposals for experiments after the May shutdown (May 1-19).  The deadline for submitting proposals for the next scheduling period (Sept-Nov) is May 31, so get your applications soon.  Remember, if you wish to do Diamond Anvil Cell work, submit to X17B3 or X17C; for DIA, Tcup, or D-DIA experiments, submit to X17B2.

Inside X17B2 hutch.  Large Volume press shown at left.  At the right is the hydraulic pump, and in the back, the control electronics.  At the far left, the movable backstop through which the beam can pass to the B3 hutch is seen.

Inside the X17B3 hutch. Round opening at the center is the beam inlet from X17B2 hutch. DAC table is seen beneath the beam inlet.

8. Searchable Directory for High Pressure Scientists

Upon requests from the community, COMPRES central office has been working on creating a directory of scientists and other professionals throughout the world working in high pressure.  We currently have about 300 names with fairly complete information.  The link to the COMPRES website page for this database is: http://www.compres.stonybrook.edu/People  Use of the database involves searching by last name.  If a match is found, then the rest of the information will be displayed.

This database also has a facility for individuals to update their entries.  To use this, enter your email address in the appropriate box and, if that email address is in the database, you can change all the other entries.

We plan to have a facility for individuals to add their names.  In the meantime, if you wish to have your name added, please send an email to michael.vaughan@sunysb.edu.  The desired information to be included for each individual is:

Note: The email address is critical because the security of future updates will be maintained using your email address.  Therefore, if you have more than one address, use the one that is most stable.

9. COMPRES membership status

COMPRES central office has received many membership applications from US and oversea institutions. So far, sixteen institutions have been approved as COMPRES members. More applications from Miami workshop attendees are expected. If your institution has not yet applied, please send in the application now. All institutions conducting Earth Science / High Pressure Science related research are welcome to join COMPRES. Members’ rights, benefits and membership application procedure can be found at COMPRES web site: http://www.compres.stonybrook.edu/People/Membership/

10. COMPRES Education and Outreach: Networking with National Organizations

For the past year, COMPRES has been collaborating as a partner in the development of a Program Plan for EarthScope’s education and outreach effort.  Glenn Richard, COMPRES’ Educational Coordinator, attended a meeting in Boulder, Colorado in February, 2002 and in Tucson in August, in order to contribute to the development of this plan, which calls for a distributed set of partners and local alliances working with the EarthScope facilities and a central office to develop and disseminate resources and offer workshops.  The local alliances and partners bring stakeholders such as educators, scientists, students and the general public into the program.  As a partner, COMPRES can provide a materials properties context for educational tools that are developed as part of the education and outreach effort.  For example, interactive digital models of fault mechanisms can be developed that include a representation of phase changes that take place in materials during seismic events.  Education programs on plate boundary phenomena can include content of the role of Earth Materials in these processes.

In 2002 and again this year, COMPRES has contributed to the planning of the Annual Meeting of the Digital Library for Earth System Education (DLESE).  As Chair of the Skills Workshop Committee, Glenn Richard has been working with members of the committee to plan a series of workshop sessions for educators, designed to familiarize them with computer-based tools that can be used for Earth Science education on all levels. The sessions also provide participants with opportunities to meet with developers of educational materials.  In the future, COMPRES will be able to offer Skills Workshops that focus on its own educational tools.  These computer-based tools in this collection can be offered to the educational community as the “Deep Earth Digital Library”.

11. COMPRES president search

The Search Committee chaired by Dave Walker of Columbia University has made great efforts in recruiting candidate for COMPRES President from the community. Advertisements have been put up in Science, EOS, the Lattice, and on internet web sites. The committee has also widely solicited the community and contacted the potential candidates. Half of the applicants are from the contacted candidates. Now the committee has narrowed down the search to two strong candidates. Names of the candidates have been submitted to the Executive Committee. Interviews will start in May, and the final decision is expected to be made in near future.

Our thanks to the Search Committee members: Raymond Jeanloz, Charles T. Prewitt, Nancy Ross, Dave Walker (Chair), Donald J. Weidner.

12. High-pressure facilities at the ALS: Call for proposals.

An approved program is in place at the Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California to allow access to synchrotron radiation for the COMPRES user community.  Initially two beamlines will be available under this program: one for high-pressure powder diffraction and one for high-pressure infrared measurements using diamond anvil cells.  The high-pressure diffraction beamline (11.3) will utilize 16keV x-rays and be equipped with a CCD detector for wide-angle monochromatic powder diffraction (further details contact Simon Clark).  The infrared beamline (1.4.3) will allow high-pressure measurements using a low profile dac on the existing infrared bench (http://infrared.als.lbl.gov).  Further details please contact Michael Martin

Applications are invited and the deadline for submission is June 1, 2003. To apply for beam time allocation, please go the following web site http://alsusweb.lbl.gov/ and open the “General Sciences Proposal and Request for Beamtime Form”, fill it out and submit the form. In the abstract section, please first type the word COMPRES followed by the abstract.

General information for new users and Proposal Wring Guidelines are located at http://www-als.lbl.gov/als/quickguide/becomealsuser.html

Reports

COMPRES Multi-anvil Cell Assembly Development

Kurt Leinenweber and James A. Tyburczy

Many of the members of COMPRES are operating multiple anvil high pressure laboratories, both in individual or small group laboratories and at synchrotron beam lines.  We estimate that there are 25-30 multianvil labs in the U.S. and many more world-wide.  COMPRES has an Infrastructure Development project based at Arizona State University devoted to working with these laboratories to improve multi-anvil cell technology.

Every multi-anvil experiment uses a cell assembly, an experimental arrangement including a ceramic pressure medium, a semiconducting ceramic or metal furnace, thermal insulation, sample sleeves, a wire thermocouple, and various other parts.  All of these parts have to fit within the cubic centimeter or smaller-sized volume that is held at high pressure during the experiment, with the sample contained inside it.  All of these parts are pressed and sintered together during the experiment, so a new assembly must be used for each experiment.  Each pressure and volume range requires a different assembly design.  Finally, for each assembly the pressure efficiency must be carefully calibrated, a process that can require as many as ten or twenty runs.

Needless to say, careful calibration requires a great deal of effort on the part of individual researchers, and consumes time and resources for each laboratory.  The main purpose of this project is to develop cell assemblies in a collaborative fashion, as a Consortium and community, in order to pool and save resources and to enable laboratories to extend their capabilities.

Some of the goals of this project are:

  1. To use the community knowledge base to develop assemblies with low failure rates, saving time and money; 
  2. To find inexpensive ways to fabricate assembly parts; 
  3. To make experiments more reproducible in pressure and temperature, increasing the precision of high-pressure studies;
  4. To make assemblies easier to put together, reducing the teaching load and experimental preparation time required for high-pressure work, and
  5. To calibrate and test the same or similar assemblies as a community, increasing the accuracy and success of experiments by sharing knowledge, 
  6. To share the knowledge and experience with the community and laboratory supervisors, as well as helping to train new generations of users.

These goals are general and abstract, and turning them into concrete action has required dividing the program into manageable parts.  The community convened at an open meeting at the Fall 2002 AGU conference, and decided to work first on an 8/3 assembly suitable for use in the 10 - 20 GPa range for distribution and testing.  During winter 2003, much work on standardization of this assembly has been performed at ASU.  The problem of cell assembly fabrication has been attacked from the “outside in.”  Paper backing for gaskets was prepared by laser-cutting (a different size for each truncation length and each cube size) and rapid milling of trapezoidal pyrophyllite pieces for gasketing has been successfully set up by a machinist hired for this project.  This creates a highly reproducible gasketing environment and reduces the amount of training needed to make assemblies.  The gasketing system can be successfully assembled by new users with virtually no explanation (like a three dimensional puzzle).

To improve the pressure medium, the significant investment in setup and formulation required for injection-molding of ceramic pressure media has been undertaken and the first octahedral pressure media have been made (Figure 1).  This technique is expected to greatly reduce the cost and is also intended to increase the reproducibility of experiments.  Testing is underway, and initial testing has given promising results (MgSiO3 perovskite has been synthesized at the expected conditions in the 8/3 assembly using the new pressure medium).

Figure 1. Injection-molded 14 mm octahedra, as made.

Cutting of metals using Electric Discharge Milling (EDM) has been undertaken for the small, difficult assemblies.  The furnace for the 8/3 assembly, the first “COMPRES assembly” adapted from Yingwei Fei’s Geophysical Lab design, is being cut precisely using this technique in order to improve the temperature reproducibility compared to using hand-cut furnaces (Figure 2).

8 mm

 
Text Box: 5.4 mm    

                            a                                                                  b

Figure 2. a.EDM-cut rhenium furnace for the 8/3 assembly, with thermocouple grooves (wide slots) and cuts for folding out the ends of the furnace (narrow slots). b. Assembly after the rhenium foil has been wrapped into a cylindrical furnace.

Even with all the new developments in these assemblies, the total cost per assembly is being kept low using this approach (relative to the traditional 1970’s-style octahedron and pregasket assembly in widespread use).  If reduced prices can be combined with an increase in success rate and precision, the benefit to our community will be significant.

We are currently actively trying to build community involvement, the heart of the whole project.  This is proceeding now with the testing of 14/8 mm injection-molded octahedra and gasketing systems at interested laboratories.  The first complete 8/3 assemblies and parts of a 10/5 assembly are expected soon.  All the parts currently in stock are available to the COMPRES community in exchange for information on their performance.  See http://multianvil.asu.edu/MainPage_Cell.html for emerging details and descriptions of parts, assemblies and new developments.  Contact Kurt Leinenweber (KurtL@asu.edu) directly for details on assembly performance.  The success of this project depends critically on input and feedback from COMPRES (and non-COMPRES) users, and we welcome your participation.

              

NICEST JINS Workshop: A Student’s Perspective

Darren Locke

Graduate Research Associate, Arizona State University

Most of us might have been slightly apprehensive about attending a workshop slated to be the “NICEST”.  One perhaps thought that a workshop with such a boastful title would fail to live up to its name.  However, the Neutrons in Solid-State Chemistry and the Earth Sciences Today and Tomorrow (NICEST) workshop held in Oak Ridge, Tennessee this past March 12-16, met all our expectations and beyond.  It was a regular melting pot of pure and cross-discipline scientists from areas such as chemistry, physics, and earth and material sciences who were either new or seasoned veterans of neutron diffraction techniques and theory. Earth science student attendance at the workshop was strong thanks to generous funding provided from the COMPRES Neutron initiative led by Nancy Ross.

The 2.5 day workshop consisted of well illustrated lectures, poster sessions, coffee break discussions, a tour of the still under construction Spallation Neutron Source (SNS) on the grounds of the Oak Ridge National Laboratory, and two short courses. A complete agenda for the meeting including speaker names and talk titles, and pictures from the workshop and short courses are included on the JINS NICEST web-site.   Information and pictures of the SNS are provided.  

Lecture topics scanned areas from the basic concepts of neutron powder/single crystal diffraction to inelastic neutron scattering. One-hour lectures were formatted to first explain, for the new users, background information followed by representative examples.  Most of us, including myself, were thankful for the introduction and background portions of the talks.  Without adequate background theory, little to nothing would have been comprehended by us new comers to the field.  I congratulate all speakers for their efforts to make their talks clear and comprehendible.

Students were provided with an opportunity to present posters at an evening session on the first night of the workshop.  Most of us that displayed posters were pleased by the attendance of seasoned veterans at this session.  Good feedback and potential areas where neutrons could benefit our research was provided.  Some projects, such as my own, had no current application of neutron techniques but were good candidates for future diffraction experiments.  For myself, being interested in hydrogen dissolved in Earth mantle minerals, the realization that these techniques exist and that facilities are available has opened many new doors for potential postdoctoral research and beyond.  In speaking with other students, we all felt that we had learned of opportunities that would allow us to utilize neutrons for our own research in the near future.                                                                                

Two short courses following the workshop were provided for both beginners and more advanced users of neutron diffraction.  These were on the use of Rietveld refinement and PDF/disordered materials, respectively.  I attended the course on Rietveld refinement that was taught by Ross Angel and Brian Toby.  Some of us in the course, including myself, had never used the General Structural Analysis Software (GSAS) or Brian Toby’s EXPGUI interface before this short course.  With lectures and guidance by Ross and Brian, most of us were successful in refining rather simple models and some even completed more difficult models in the 1.5 day short course. 

My impressions of the use of neutrons by Earth scientists at facilities around the United States and Europe following the workshop were very positive.  I think that I speak for many young Earth scientists, studying the structure and deformation of earth materials, when I say that advances in neutron diffraction techniques open a new and exciting door for today and the future.  As we strive to gain knowledge of deep Earth mantle processes, intense x-ray and neutron sources will provide data on, among many others, new mineral structures and location of impurity atoms that effect the strength of minerals at high pressure and temperature.  

Coming Events

Second COMPRES annual meeting, Santa Cruz, June 18-20

The dates for the Second COMPRES Annual Meeting have been set for June 18-20, 2003 (Wednesday-Friday). Please block these days on your calendar and plan to attend. A reception will start on the evening of Tuesday, June 17. The meeting will be held at the Coast Santa Cruz Hotel, 175 West Cliff Drive, Santa Cruz, CA. (831) 426-4330. All members of COMPRES are encouraged to attend. Those who are participating in COMPRES projects, or who have performed experiments at COMPRES facilities should plan to submit an abstract and present a poster on their work. The cost of hotel rooms for 3 nights and some meals will be covered for all participants. Students are strongly encouraged to attend this meeting. Some support for student might be available. Please contact Jay Bass to apply for student assistance. The local organizers are Quentin Williams and Elise Knittle. The contact person at UCSC is Ms. Judy Van Leuzen, 831-459-4137. Please check the COMPRES web site for updated information.

Workshops at the 2003 NSLS Annual Users' Meeting, High Pressure Mineral Physics Using Synchrotron Radiation, Upton, New York, May 21

The workshop will introduce most techniques for probing materials using synchrotron radiation at high pressures and temperatures. These techniques include diffraction (both energy-dispersive using white radiation and angle-dispersive using white radiation); radiographic imaging; ultrasonic interferometry; stress and strain measurements; infrared spectroscopy; Raman spectroscopy; and inelastic scattering.  Presentations will also be made discussing scientific applications of these techniques. Visit the workshop web site for the list of speakers and more details at http://nslsweb.nsls.bnl.gov/nsls/users/meeting/2003/workshop5-HighPressure.htm.

Opportunities

Postdoctoral Research Associate/Mineral Physics

Princeton University

Applications are invited for a post-doctoral research position in mineral physics in the Department of Geosciences at Princeton University.   Qualifications include a Ph.D. in Geoscience, Physics, Materials Science or a related field as well as experience/interests in some or all of the following areas: diamond anvil cell techniques, laser heating, synchrotron x-ray diffraction, and Brillouin scattering. Research opportunities are available in development of advanced laser heating systems for use with the diamond anvil cell, ultra-high pressure-temperature experiments using synchrotron x-ray diffraction techniques, and high-pressure elasticity measurements using Brillouin spectroscopy.  The position is for one year with a possible renewal for an additional year.  Candidates should send a letter of application, resume, research statement, list of publications, and names of three references to: Professor T. Duffy, Department of Geosciences, Princeton University, Princeton, NJ 08544  (609-258-6769).  Princeton University is an Affirmative Action/Equal Opportunity employer.

University of Illinois

Applications are invited for a full-time post-doctoral research associate in the general field of high-pressure mineral physics. Research will involve Brillouin scattering measurements of sound velocities in mantle minerals and/or high pressure x-ray research using synchrotron radiation. Familiarity with high pressure research, especially using diamond anvil cells, x-ray diffraction, and a PhD are required. Experience with Brillouin scattering is desirable but not necessary. The starting date is negotiable but the position is available immediately. Applicants should send a CV, list of publications, and the names of at least 3 references to: Jay Bass, Department of Geology, University of Illinois, 1301 W. Green St., Urbana, IL 61801 (217-333-1018). The University of Illinois is an EO/AA employer.

Stony Brook University

The Mineral Physics Institute at Stony Brook University in conjunction with COMPRES grand challenge programs is accepting applications for postdoctoral research associates.  These non-tenured appointments will be for one year with possible renewal for an additional year. Successful applicants will be expected to work with our research programs in high pressure rheology, elasticity and synchrotron X-ray studies using existing facilities in the High Pressure Laboratory and analytical laboratories of the Mineral Physics Institute and in situ X-ray diffraction using synchrotron radiation installations at Brookhaven National Laboratory and APS - Argonne National Laboratory. Applications are invited at any time. We encourage candidates to develop a research plan with an Institute staff member.  Women and minorities are encouraged to apply.  Candidates should send curriculum vita, a statement of research plan, and arrange for three letters of reference to be sent to: Ann Lattimore, Mineral Physics Institute, ESS Bldg. SUNY, Stony Brook, NY 11794-2100 (631-632-8213). The University at Stony Brook is an Affirmative Action/Equal Opportunity educator and employer.

Communication and Newsletter input

            Our Newsletter aims to pave an information superhighway between institutions, and inspire communications among COMPRES members. Your input will be helpful to improve the quality of the Newsletter, and increase our effectiveness on the superhighway.  Please contact us with your suggestions for newsletter items or comments.

COMPRES Contacts

President, Jay Bass, (217)333-1018, bass@hercules.geology.uiuc.edu

Chair, Donald J. Weidner, (631)632-8211, Donald.Weidner@sunysb.edu

Administration, Ann Lattimore, (631)632-8213, alattimore@notes.cc.sunysb.edu

Newsletter, Jiuhua Chen, (631)632-8058, Jiuhua.Chen@sunysb.edu