Structure of Non-crystalline Iron at High Pressures and Temperatures

Guoyin Shen, Vitali Prakapenka, Mark Rivers, Steve Sutton, University of Chicago

APS-GSECARS

Ninety-six percent of the Earth's core by volume is in a liquid state. Knowledge of the behavior of liquid iron at high pressures and temperatures is geophysically important. With the development of synchrotron facilities, direct measurements on structures of non-crystalline materials become feasible at high pressures and high temperatures. Information on the local structure (microscopic data) provides a basis for understanding numerous macroscopic properties such as compressibility and viscosity.
We report our recent results on (1) room temperature compression of amorphous iron up to 67 GPa, and (2) the structure of liquid iron at high pressures and high temperatures. The experiments were performed using a modified diamond anvil cell (DAC) that allows measurements of x-ray scattering to a maximum momentum of 86 1/nm using a monochromatic beam at a wavelength of 0.3311 Å. It is shown that accurate structural determination can be made on amorphous materials in a DAC to ultra high pressures.